A radiator cap is a crucial component in a vehicle's cooling system, designed to maintain the system's pressure and ensure efficient engine cooling. It functions as a pressure release valve, typically set to a specific pressure rating, usually between 13 to 16 psi for most vehicles. 
When the engine operates, the coolant heats up and expands, increasing the pressure within the cooling system. The radiator cap's spring-loaded valve remains closed until the pressure reaches the cap's predetermined limit. At this point, the valve opens slightly, allowing excess coolant to flow into the overflow reservoir. This prevents the system from exceeding its pressure limit, which could otherwise lead to hose or radiator damage.
As the engine cools down, the coolant contracts, creating a vacuum in the system. The radiator cap has a secondary valve, often called a vacuum valve, which opens to allow coolant from the overflow reservoir to return to the radiator. This process ensures that the system remains full of coolant and prevents air from entering, which could cause overheating or inefficient cooling.
By maintaining the correct pressure, the radiator cap raises the boiling point of the coolant, allowing the engine to operate at higher temperatures without boiling over. This is crucial for maintaining optimal engine performance and preventing overheating. The cap's ability to regulate pressure and facilitate coolant flow between the radiator and overflow reservoir ensures the cooling system operates efficiently, protecting the engine from thermal damage.